The entire process incl. Number Portability ran flawlessly.
Somewhat confusingly, the info was in an email that the PIN and PUK will be sent by mail, but then must be retrieved in the service world. In another e-mail, however, it is said that the world service is available only from the porting date. That's something contradictory.
Apart from DeutschlandSIM is very customer-friendly. All actions are confirmed directly by e-mail. The shipping from Amazon worked perfectly.